We have already studied intramolecular bonds in molecules now, we will examine intermolecular forces of attraction in liquids and solids.
This is called the metallic bond.
In a group, metallic bond strength generally decreases from up to down.
In a period, strength generally increases from left to right.
Electrostatic attraction occurs between
the positive and negative charges holding the ions together.
Metal ions are surrounded by nonmetal ions and nonmetal ions surrounded by metal ions.
The hardest natural substance.
The bonds are formed by sp3-sp3 hybrid overlap.
The bonding involves sp2 – sp2 hybrid overlap.
Because of weak bonding between the layers, the layers can slide over each other.
Conduct electricity.
H2O ,HCl , NH3, H2S , PH3 , SO2 are samples.
Dipole - dipole force is much weaker than the covalent bond within the molecule.
By movement of electrons, nonpolar molecules becomes temporarily polar.
The momentarily polar molecule makes polar its neighboring molecule.
Thus a weak attraction occurs between the molecules.
Van der Waals forces are stronger between molecules with high molecular masses.
For small molecules, the van der Waals force is weaker than dipole - dipole forces and hydrogen bonding.
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